Product ID:PREMIUM LEADED GASOLINE
MSDS Date:12/28/1987
FSC:9130
NIIN:01-207-7039
MSDS Number: BMZLY

DIAMOND SHAMROCK REFINING AND MARKETING CO.

9830 COLONADE BLVD.
SAN ANTONIO, TX 78269-6000
US

Emergency Phone: 512-641-8800

Info Phone: 512-641-8800

Cage: 3P045

DIAMOND SHAMROCK REFINING AND MARKETING CO

696000 SAN ANTONIO, TX 78269-6000 US

Telephone: 210-641-8601

Cage: 3P045

GASOLINE (TO INCLUDE INGREDIENTS 2 THRU 10)

CAS: 8006-61-9

RTECS: LX3300000

Fraction By Weight: 100%

OSHA PEL 300 PPM/500 STEL

ACGIH TLV: 300 PPM/500STEL;9192

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: 5% %

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9192

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

TETRAETHYL LEAD (SARA III)

CAS: 78-00-2

RTECS: TP4550000

OSHA PEL S, 0.075MG/M3(PB)

ACGIH TLV: S, 0.1 MG/M3(PB)9192

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

1,2,4-TRIMETHYLBENZENE (SARA III)

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: 2 - 5%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9192

MESITYLENE

CAS: 108-67-8

RTECS: OX6825000

Fraction By Weight: 1% %

METHYL TERT-BUTYL ETHER (SARA III)

CAS: 1634-04-4

RTECS: KN5250000

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

ETHYL BENZENE (SARA III)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: < 2% %

OSHA PEL 100 PPM/125 STEL

ACGIH TLV: 100 PPM/125STEL 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: < 9% %

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TRIMETHYL BENZENE (SARA III)

CAS: 25551-13-7

RTECS: DC3220000

Fraction By Weight: < 4.5% %

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9192

METHYL TERT-BUTYL ETHER (SARA III)

CAS: 1634-04-4

RTECS: KN5250000

Fraction By Weight: 0 - 15%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

LD50 LC50 Mixture:ORAL RAT 18,800 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:PRODUCT IS IRRITATING TO EYES,SKIN
RESPIRATORY TRACT AND DEPRESSES THE CENTRAL NERVOUS SYSTEM. CHRONIC
OVER EXPOSURE MAYN CAUSE LIVER,KIDNEY, OR CENTRAL NERVOUS SYSTEM
DAMAGE.
Explanation of Carcinogenicity:CONTAINS LEAD & BENZENE;LISTED BY ALL
THREE. ALSO,AN API STUDY FOUND LIVER CANCER IN MICE EXPOSED TO
GASOLINE VAPORS.
Effects of Overexposure:EYE/SKIN CONTACT:TRANSISTORY IRRITATION.
INHALED:RESPIRATORY IRRITATION,CENTERAL NERVOUS SYSTEM DEPRESSION
INCLUDING,EUPHORIA,HEAFACHE,DIZZINESS,DROWINESS,FATIGUE,TREMORS,
CONVULSIONS,NAUSEA,VOMITING, DIARRHEA,LOSS OF CONSCIOUSNESS.AND
FINALLY DEATH.INGESTED:G/I IRRITATION,PLUS SYMPTOMS SIMILAR TO
THOSE UNDER "INHALEDE"
Medical Cond Aggravated by Exposure:PRE-EXISTING EYE,SKIN CONDITIONS OR
IMPAIRED LIVER,KIDNEY FUNCTION MAY BE AGGRAVATED BY THIS PRODUCT.

First Aid:EYE:FLUSH WITH WATER 15 MIN. SKIN:WASH WITH SOAP & WATER.
REMOVE CONTAMINATED CLOTHING;LAUNDER BEFORE REUSE. INHALED: REMOVE
TO FRESH AIR. RESUSCITATE OR GIVE OXYGEN AS NEEDED. GET MEDICAL
CARE. INGES TED:GET IMMEDIATE MEDICAL ATTENTION. DONOT INDUCE
VOMITING. IF VOMITING OCCURS,MINIMIZE ASPIRATION HAZARD.

Flash Point:AMBIENT TEMP
Lower Limits:1.3
Upper Limits:7.6
Extinguishing Media:DRY CHEMICAL,CARBON DIOXIDE,FOAM,WATER FOG. WATER
MAY BE INEFFECTIVE,AS PRODUCT WILL FLOAT AND WHY SPREAD FIRE.
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS IN
ENCLOSED AREAS. WATER SPRAY MAY BE USED TO COOL FIRE EXPOSED
CONTAINERS.
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER TAN AIR,ACCUMULATING
IN LOW AREAS,TRAVELING ALONG GROUND AND MAY FLASH BACK FROM DISTANT
IGNITION SOURCE.

Spill Release Procedures:ELIMINATE IGNITION SOURCES. ISOLATE AREA. USE
PROTECTIVE EQUIPMENT AS NECESSARY. STOP LEAK AND CONTAIN SPILL.
DIKE AS NEEDED TO KEEP SPILL FROM DRAINS,WATER WAYS ETCS. WATER FOG
MAY BE USED TO REDUCE VAPORS & PERSONAL HAZARD. REPORT SPILL PER
LAW.
Neutralizing Agent:NONE

Handling and Storage Precautions:STORE IN A COOL,DRY,ISOLATEED,WELL
VENTILATED AREA. KEEP IGNITION SOURCES AWAY. GROUND CONTAINERS TO
PREVENT STATIC DISCHARGE DURING TRANSFERS.
Other Precautions:FIRE AND EXPLOSION ARE THE ACUTE HAZARDS OF THIS
PRODUCT. TAKE EXTRAORDINARY STEPS TO PREVENT THEM.

Respiratory Protection:IF NEEDED USE, NIOSH/MSHA RESPIRATOR WITH
ORGANIC NAPOR CARTRIDGE OR PREFERRABLY,APOSITIVE PRESSURE AIR
SUPPLIED RESPIRATOR OR SELF CONTAINED BREATHING APPARATUS.
Ventilation:USE EXPLOSION PROOF VENTILATION EQUIPMENT TO MAINTAIN
EXPOSURE BELOW PEL/TLV.
Protective Gloves:IMPERVIOUS RUBBER OR POLYMER.
Eye Protection:SAFETY GLASSES,OR SPLASH GOGGLES.
Other Protective Equipment:SAFETY SHOWER/EYE WASH. WORK CLOTHING AS
NEEDED TO PROTECT FROM PROLOMGED/REPEATED CONTACT.
Work Hygienic Practices:USE GOOD CHEMICAL HYGIENE PRACTICE. AVOID
UNNECESSARY CONTACT. MINIMIZE ALL CONTACT.
Supplemental Safety and Health
MSDS NO. M4039.

HCC:F2
Boiling Pt:B.P. Text:80-437
Vapor Pres:9-15 PSI
Vapor Density:3.5 (AIR)
Spec Gravity:0.72 - 0.76
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR,COLORLESS TO STRAW YELLOW LIQUID;GASOLINE
ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:HEAT,SPARKS AND OTHER IGNITION
SOURCES,VAPOR ACCUMULATIONS.
Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE

Waste Disposal Methods:DISPOSE I/A/W FEDERAL,STATE,LOCAL REGULATIONS.
PRODUCT QUALIFYS AS IGNITABLE WASTE AND CANNOT BE LANDFILLED. IF
RECOVERY OR RECYCLE ARE UNACCEPTABLE, INCINERATION MAY BE
ACCEPTABLE DISPOSAL METHOD.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.